Synthetic Control over Ligand-Field Photophysics and Photooxidation Potentials in Cr(III) Chromophores.
The ambiguous design rules for controlling light absorption, photoluminescence (PL) emission, and excited-state decay in pseudo-octahedral Cr(III) chromophores pose key challenges for their implementation as photosensitizers in photocatalysis and optoelectronic applications. Tailored metal-ligand interactions ultimatel...