Elucidation of Macrocycle-Derived Covalent Organic Framework Film Formation through Interfacial Linker Exchange.
Over the past decade, postsynthetic linker exchange (PLE) has emerged as a promising strategy for fabricating high-quality covalent organic frameworks (COFs), leveraging the principles of dynamic covalent chemistry (DCC). However, the synthetic challenges posed by the complex parent entities used in PLE, such as COFs a...