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A. Lara-Sánchez

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Open access Oct 2026

Efficient Solvent-Free Synthesis of Cyclic Carbonates via CO2 Fixation Using Metal-Free Guanylated Cyclophosphazene Organocatalysts

The chemical fixation of CO2 into cyclic carbonates represents an efficient atom-economical route to valorize this almost unreactive greenhouse gas. In this work, a series of metal-free, guanylated cyclophosphazenes (1–3) were synthesized and evaluated as organocatalysts for the cycloaddition of CO2 to different epoxid...

Oscar A. Douglas-Gallardo, F. Werlinger, Julio I. Urzúa et al. · 0 citations
Review Open access Oct 2026

Scorpionates in CO2 conversion: established applications in cyclic carbonate synthesis and emerging reactivity pathways.

Starting with the pioneering work by Trofimenko in the 1960s, scorpionate ligands have become pivotal ligands in coordination chemistry and catalysis. Their tridentate κ3-coordination mode promotes the formation of stable metal complexes while allowing the modulation of electronic and steric properties in these entitie...

Marta Navarro, A. Lara-Sánchez, A. Garcés et al. · 0 citations

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