Cooperative Enantiomorphic-Site and Chain-End Chirality in Isoselective β-Lactone Polymerization
Polymer properties are profoundly impacted by tacticity, necessitating an understanding of the origins of stereocontrol to make high-performance materials. Recently, we reported that controlled incorporation of stereoerrors into trans-poly(3-hydroxy-2-methylbutyrate) (trans-PHMB) through the isoselective polymerizati...