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Open access Aug 2026

Resolving Competing Ultraviolet Photoinduced Ring-Opening and Dissociation Pathways in Iodothiophenes by Ultrafast Electron Diffraction

The ultraviolet photochemistry of halothiophenes is thought to proceed via competing pathways, prompt C–X (X = halogen) bond fission, and parent ring opening followed by fragmentation, yet direct structural evidence distinguishing these mechanisms is limited. Here, time-resolved gas-phase ultrafast electron diffracti...

A. Ghrist, Matthew Bain, Yu-Song Liu et al. · 0 citations
Preprint Aug 2026

Tracking molecular hydrogen formation from ionized water in real time

Removing an electron from a water molecule can drive its two hydrogen atoms to pair up and depart as molecular hydrogen. However, even for this elementary reaction, the route from start to finish has remained hidden because measurements have yet to follow the electronic and nuclear motion simultaneously. Combining corr...

Chuan Cheng, Chi-Hong Yuen, E. Weckwerth et al. · 0 citations

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