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A. Ganesan

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Open access Aug 2026

Total Synthesis of the Antifungal Clinical Candidate ASP2397 Cyclohexapeptide Facilitated by the Chemo-selective Reduction of Secondary N -Benzyloxyamides

ASP2397 is a siderophore-like cyclic hexapeptide with potent and rapid fungicidal activity against Aspergillus species. We report here its first total synthesis, enabled by an unprecedented one-pot chemoselective reduction of secondary N-benzyloxyamides that strictly preserves the fragile N–O bond. This transformatio...

Mohamed Osama Ibrahim Mohamed, Yue Du, K. Ohsawa et al. · 0 citations

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